Electroactive properties of supramolecular complexe of alkyldimethylbenzylammonium chlorides and polyoxomolibdate
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Author |
Mironyak M. O., Volnyanska O. V., Manzuk M. V., Kats A. A., Labyak O. V. and Nikolenko M. V.
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e-ISSN |
1819-6608 |
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On Pages
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446-451
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Volume No. |
19
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Issue No. |
7
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Issue Date |
May 30, 2024
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DOI |
https://doi.org/10.59018/042461
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Keywords |
alkylbenzyldimethylammonium chloride, benzalkonium chloride, catamine AB, electroactive substance, membrane, 12-molybdophosphate acid, polyoxometalates, supramolecular complexes.
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Abstract
Electroactive supramolecular complexes based on alkylbenzyldimethylammonium chloride and polyoxometalates have been obtained. To study the electroactive properties of supramolecular complexes, plasticized polyvinyl chloride membranes were obtained. Anions of 12-molybdophosphate heteropolyacid were used as polyoxometalates. The electroactive characteristics of the resulting membranes (angle of inclination, linearity of the electrode function, minimum detectable concentration) were studied depending on the content of supramolecular complexes in it, the nature of the solvent-plasticizer of the membrane, and the pH of the solution under study. Rational conditions for obtaining membranes based on supramolecular complexes have been established. The resulting membranes can be used to develop potentiometric sensors for the determination of benzalkonium chloride salts in industrial products and environmental objects.
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